{"id":2677,"date":"2018-04-29T09:08:18","date_gmt":"2018-04-29T06:08:18","guid":{"rendered":""},"modified":"2018-04-29T09:08:18","modified_gmt":"2018-04-29T06:08:18","slug":"","status":"publish","type":"post","link":"https:\/\/coeng.uobaghdad.edu.iq\/?p=2677","title":{"rendered":"\u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0629 \u0633\u0645\u0627 \u0645\u062d\u0645\u062f \u0639\u0628\u062f\u0627\u0644\u0644\u0647 \u0627\u0644\u062a\u062f\u0631\u064a\u0633\u064a\u0629 \u0641\u064a \u0642\u0633\u0645 \u0627\u0644\u0647\u0646\u062f\u0633\u0629 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0648\u064a\u0629 \u062a\u0646\u0634\u0631 \u0628\u062d\u062b\u0627\u064e \u0641\u064a \u0645\u062c\u0644\u0629 \u0645\u0635\u0646\u0641\u0629 \u0636\u0645\u0646 \u0627\u0644\u0645\u0633\u062a\u0648\u0639\u0628\u0627\u062a \u0627\u0644\u0627\u0631\u0628\u0639."},"content":{"rendered":"
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\u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0629 \u0633\u0645\u0627 \u0645\u062d\u0645\u062f \u0639\u0628\u062f\u0627\u0644\u0644\u0647 \u0627\u0644\u062a\u062f\u0631\u064a\u0633\u064a\u0629 \u0641\u064a \u0642\u0633\u0645 \u0627\u0644\u0647\u0646\u062f\u0633\u0629 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0648\u064a\u0629 <\/span>\u062a<\/span>\u0646\u0634\u0631 \u0628\u062d\u062b\u0627\u064e \u0641\u064a \u0645\u062c\u0644\u0629 \u0645\u0635\u0646\u0641\u0629 \u0636\u0645\u0646 \u0627\u0644\u0645\u0633\u062a\u0648\u0639\u0628\u0627\u062a \u0627\u0644\u0627\u0631\u0628\u0639.<\/span><\/p>\n

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\u0642\u0627\u0645\u062a \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0629 \u0633\u0645\u0627 \u0645\u062d\u0645\u062f \u0639\u0628\u062f\u0627\u0644\u0644\u0647 \u0627\u0644\u062a\u062f\u0631\u064a\u0633\u064a\u0629 \u0641\u064a \u0642\u0633\u0645 \u0627\u0644\u0647\u0646\u062f\u0633\u0629 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0648\u064a\u0629 \u0648\u0627\u0644\u062d\u0627\u0635\u0644\u0629 \u0639\u0644\u0649 \u0634\u0647\u0627\u062f\u0629 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0629 \u0645\u0646 \u062c\u0627\u0645\u0639\u0629 \u0645\u0627\u0646\u0634\u0633\u062a\u0631 \u0641\u064a \u0628\u0631\u064a\u0637\u0627\u0646\u064a\u0627 \u0628\u0646\u0634\u0631 \u0628\u062d\u062b\u0647\u0627 \u0627\u0644\u0645\u0648\u0633\u0648\u0645 <\/span><\/p>\n

Understanding the seeding mechanism of hierarchically porous zeolite\/carbon composites<\/span><\/p>\n

\u0641\u064a \u0645\u062c\u0644\u0629 <\/span>Microporous and Mesoporous Materials<\/span>  \u0627\u0644\u062a\u0627\u0628\u0639\u0629 \u0644\u062f\u0627\u0631 \u0627\u0644\u0646\u0634\u0631<\/span>Elsevier<\/span> \u0648\u0627\u0644\u0645\u0635\u0646\u0641\u0629 \u0636\u0645\u0646 \u0645\u0633\u062a\u0648\u0639\u0628 <\/span>Scopus<\/span>. \u0639\u0644\u0645\u0627 \u0623\u0646 \u0627\u0644\u062f\u0643\u062a\u0648\u0631\u0629 \u0633\u0645\u0627 \u0645\u062d\u0645\u062f \u0639\u0628\u062f\u0627\u0644\u0644\u0647 \u0644\u062f\u064a\u0647\u0627 \u062b\u0644\u0627\u062b\u0629 \u0639\u0634\u0631 \u0628\u062d\u062b \u0645\u0646\u0634\u0648\u0631 \u0648\u0633\u0628\u0639\u0629 \u0628\u062d\u0648\u062b \u0645\u0646\u0647\u0627 \u0645\u0646\u0634\u0648\u0631\u0629 \u0636\u0645\u0646 \u0627\u0644\u0645\u0633\u062a\u0648\u0639\u0628\u0627\u062a \u0627\u0644\u0627\u0631\u0628\u0639\u0629.<\/span><\/p>\n

 <\/span><\/p>\n

\u0645\u0644\u062e\u0635 \u0627\u0644\u0628\u062d\u062b:<\/span><\/p>\n

\u064a\u062a\u0646\u0627\u0648\u0644 \u0627\u0644\u0628\u062d\u062b \u0639\u0631\u0636 \u0637\u0631\u064a\u0642\u0629 \u062c\u062f\u064a\u062f\u0629 \u0641\u064a \u062a\u062d\u0636\u064a\u0631 \u062e\u0644\u0627\u0626\u0637 \u0627\u0644\u0632\u064a\u0648\u0644\u0627\u064a\u062a-\u0643\u0627\u0631\u0628\u0648\u0646 \u0630\u0627\u062a \u0627\u0644\u062a\u0631\u0643\u064a\u0628 \u0627\u0644\u0645\u0633\u0627\u0645\u064a \u0627\u0644\u0647\u0631\u0645\u064a \u0628\u0648\u0627\u0633\u0637\u0629 \u0627\u0644\u062a\u062d\u0641\u064a\u0632 \u0627\u0644\u0645\u064a\u0643\u0627\u0646\u064a\u0643\u064a \u0644\u0633\u0637\u062d \u0627\u0644\u062d\u0627\u0645\u0644 \u0627\u0644\u0643\u0627\u0631\u0628\u0648\u0646\u064a \u0628\u0623\u0633\u062a\u062e\u062f\u0627\u0645 \u062c\u0633\u064a\u0645\u0627\u062a \u0645\u062a\u0646\u0627\u0647\u064a\u0629 \u0627\u0644\u0635\u063a\u0631 (<\/span>nanoparticle suspensions<\/span>). \u062d\u064a\u062b \u0643\u0627\u0646 \u064a\u0639\u062a\u0642\u062f \u0627\u0646 \u0627\u0644\u0632\u064a\u0648\u0644\u0627\u064a\u062a \u0627\u0644\u0645\u0631\u0627\u062f \u062a\u062d\u0636\u064a\u0631\u0647 \u064a\u062c\u0628 \u0623\u0646 \u064a\u0636\u0627\u0641 \u0628\u0634\u0643\u0644 <\/span>Seeds<\/span>. \u0644\u0643\u0646 \u0641\u064a \u0647\u0630\u0647 \u0627\u0644\u0628\u062d\u062b \u062a\u0645 \u062f\u0631\u0627\u0633\u0629 \u062a\u0623\u062b\u064a\u0631 \u0627\u0644\u062c\u0633\u064a\u0645\u0627\u062a \u0627\u0644\u0645\u062a\u0646\u0627\u0647\u064a\u0629 \u0627\u0644\u0635\u063a\u0631 \u0639\u0644\u0649 \u0628\u0644\u0648\u0631\u0629 \u0627\u0644\u0632\u064a\u0648\u0644\u0627\u064a\u062a \u0648\u0627\u0644\u062a\u064a \u062a\u0639\u0645\u0644 \u0639\u0644\u0649 \u062a\u0643\u0648\u064a\u0646 \u0634\u0642\u0648\u0642 \u0641\u064a \u0633\u0637\u062d \u0627\u0644\u062d\u0627\u0645\u0644 \u0644\u062a\u0642\u0648\u0645 \u0628\u062f\u0648\u0631 \u0645\u0631\u0627\u0643\u0632 \u062a\u0628\u0644\u0648\u0631 \u0644\u0644\u0632\u064a\u0648\u0644\u0627\u064a\u062a. \u062d\u064a\u062b \u062a\u0645 \u0623\u062b\u0628\u0627\u062a \u0623\u0647\u0645\u064a\u0629 \u0648\u062c\u0648\u062f \u0647\u0630\u0647 \u0627\u0644\u062c\u0633\u064a\u0645\u0627\u062a \u0623\u062b\u0646\u0627\u0621 \u0627\u0644\u062a\u062d\u0641\u064a\u0632 \u0627\u0644\u0645\u064a\u0643\u0627\u0646\u064a\u0643\u064a \u0628\u0648\u0627\u0633\u0637\u0629 <\/span>Ultrasonication<\/span> \u0645\u0647\u0645\u0627 \u0643\u0627\u0646 \u0645\u0635\u062f\u0631 \u0647\u0630\u0647 \u0627\u0644\u062c\u0633\u064a\u0645\u0627\u062a.
<\/span><\/p>\n

Abstract<\/span><\/h2>\n
\n

Recent research has demonstrated a new synthesis route for hierarchically porous zeolite composites by mechanical modification of the support surface using ultrasonication in a nanoparticle<\/a> suspension. It was believed that target <\/span>zeolites<\/a> should be added as seeds for the sonication. In this study, the effect of nanoparticles was investigated with ultrasonication to understand the crystallization<\/a> mechanism of zeolites obtained by the nanoparticles–assisted synthesis. It has been found that the nanoparticles under the influence of ultrasonication generate fissures or cracks as <\/span>nucleation<\/a> sites on the carbon surface<\/a>. These nanoparticles such as zeolite A, γ-Al<\/span><\/span><\/span>2<\/sub>O3<\/sub>, quartz<\/a> and sand are different from the target zeolite X. Therefore, an amorphous <\/span>aluminosilicate<\/a> gel nucleates at those cracks during the hydrothermal treatment. Thus, the mechanical activation<\/a> of the support surface is the process to induce the formation of strongly attached zeolite X over the template, not a seeding step. This is confirmed as an attachment due to the weak bond between the support and the zeolite for ‘non-seeded’ composites whereas the ‘seeded’ composites have a robust structure which maintains a zeolite coating upon mechanical agitation.<\/span><\/span><\/span><\/p>\n<\/p><\/div>\n

<\/p>\n


https:\/\/www.sciencedirect.com\/<\/wbr>science\/article\/pii\/<\/wbr>S1387181118302026<\/a>
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\"\" <\/span><\/p>\n<\/p><\/div>\n

\"\" <\/div>\n","protected":false},"excerpt":{"rendered":"

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